Very odd ...
Your Display Properties should look like this ... note the Display: ...
Matrox Triplehead2Go Digital Edition on NVIDIA ... etc.
It seems that you do not have the Matrox display driver installed (or it isn't installed correctly)
Try this ...
Go to ... Display Properties ... Settings ...
Click the "Advanced" button ...
Click the "Monitor" tab ...
Click the "Properties" button ...
Click .the "Update Driver" button ...
Choose ... Not at this time ... next ...
Choose ... "Install from a specific location" ...
Choose ... "Don't search. I will choose the driver to install"
Click ... "Have Disk" ...
Browse/navigate to your PowerDesk install directory ... usually ...
C:Program FilesMatrox Graphics IncPowerDesk SE
Highlight the file ...
GXM.inf
Click ... Open
You may get a pop up asking if you trust Matrox ... if you do ... answer ... yes.
This should install the Matrox display drivers and once you have re-booted the computer you should be able to choose TripleHead resolutions.
Let me know how you get on ... 8)